RT info:eu-repo/semantics/article T1 Electromethanogenesis at medium-low temperatures: Impact on performance and sources of variability A1 Pelaz Guerra, Guillermo A1 Carrillo Peña, Daniela Andrea A1 Morán Palao, Antonio A1 Escapa González, Adrián A2 Ingenieria Electrica K1 Ingeniería química K1 Bioelectrochemical system K1 Electromethanogenesis K1 Low temperature K1 Biogas K1 Biocathode K1 3303 Ingeniería y Tecnología Químicas K1 3306 Ingeniería y Tecnología Eléctricas AB [EN] In this study we aimed to understand the impact of medium–low temperatures on the two main steps that usually comprise the electromethanogenesis (EM) process: electrothrophic hydrogenesis and hydrogenothrophic methanogenesis. Results revealed that pure CO2 could effectively be converted into a high-purity biogas (∼90:10 CH4/CO2) at 30 °C. However, when temperature was reduced to 15 °C, methane richness greatly decreased (∼40:60 CH4/CO2). This deterioration in performance was mostly attributed to a decline in methanogenic activity (represented mainly by Methanobacterium and Methanobrevibacter). In contrast, the hydrogenic activity (mostly Desulfomicrobium) did not suffer any significant decay. Results also seemed to indicate that methanogenesis, rather than hydrogenesis, is the main source of variability in EM. Increasing the temperature again to 30 °C restored previous performance, which highlights the resilience of EM to wide temperature fluctuations (from 30 to 15 and back 30 °C). PB Elsevier SN 0016-2361 LK http://hdl.handle.net/10612/14445 UL http://hdl.handle.net/10612/14445 DS BULERIA. Repositorio Institucional de la Universidad de León RD 25-abr-2024